These two images are taken within minutes of each other. The beauty of the digital camera is taking multiple shots and being able to see the results almost immediately. While I like the colouration of the second image better, the first one is composed better by framing in the sunset.
In post production, I would also increase the saturation of the orange to make it pop more. Here is what that looks like. I increased the saturation of the orange sky, increased the blackpoint, and added a bit of exposure as well.